I think because arXiv can have a DOI identifier set when authors publish, it would be nice to import that as well.
My guess is that it is a simple modification in
src/java/net/sf/jabref/imports/OAI2Handler.java
Around line 76 add something like:
} else if (qualifiedName.equals("doi")) {
followed by the necessary entry.setField for doi in Bibtex.