The links at http://starship.python.net/crew/mhammond/win32/ in the section
"""
There is also some (old) documentation you may like to check out. For some details on Pythonwin (including embedding it in your own MFC application and some MFC concepts) see http://www.python.org/windows/pythonwin/. For some overviews of the Win32 API as exposed to Python, see http://www.python.org/windows/win32/
"""
are dead.
Searching for "win32" at python.org brings up http://www.python.org/ftp/python/win32/ which just says
"""
Do yourself a favor and pick up a newer Python download for Windows!
Go to http://www.python.org/download/ for the latest versions.
"""
Not very helpfull too.
Is there win32 API doc online somewhere?