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#1326 Normalization for Hydrogen Wave Functions

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nobody
5
2008-06-15
2008-01-06
Anonymous
No

When trying to show that the hydrogen wave functions are normalized you do not always get a 1. Frequently you get an expression that upon further evaluation manually works out to 1. Maxima fails to get that 1.

Maxima version: 5.14.0Maxima build date: 21:46 12/27/2007host type: i686-pc-mingw32lisp-implementation-type: GNU Common Lisp (GCL)lisp-implementation-version: GCL 2.6.8.

rvh2006@cavtel.net

Rich Hennessy

Discussion

  • Nobody/Anonymous

    Hydrogen Wave Function Definitions

     
  • Raymond Toy

    Raymond Toy - 2008-01-07

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    Not the best solution, but Y is the only part that contains exp(%i*foo) so conjugate(%Psi[n,l,m](x,y,r)) is the same as %Psi[n,l,m](x,-y,r). If you use this in your integration, all of the integrals do work out to 1.

     
  • Barton Willis

    Barton Willis - 2008-01-08

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    For another solution, see /share/orthopoly/h_atom.dem.

     
  • Anonymous

    Anonymous - 2008-01-09

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    Where is "/share/orthopoly/h_atom.dem" Is this a website?

    Rich

     
  • Barton Willis

    Barton Willis - 2008-01-09

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    No, it's not a website. Try this:

    (%i4) batch("h_atom.dem");
    batching #pC:/PROGRA~1/MAXIMA~1.0/share/maxima/5.14.0/share/orthopoly/h_atom.dem

     
  • Nobody/Anonymous

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    Changing the y term to -y works for me. I can use that in general for complex valued functions by changing my functions to have one more variable f(x, y, z) --> f(x, y, z, sign). Then white %i as sign*%i everywhere in the function where there is an %i. f(x, y, z, 1)*f(x, y, z, -1) would do it. I think that works all the time unless there is no %i in the function definition (it could still be complex).

    Rich
    rvh2006@cavtel.net

     
  • Robert Dodier

    Robert Dodier - 2008-06-15

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    I don't see a specific bug report here, and I'm much too lazy to try to puzzle it out. Closing this report.

     
  • Robert Dodier

    Robert Dodier - 2008-06-15
    • status: open --> closed
     
  • Robert Dodier

    Robert Dodier - 2008-06-15

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    Forgot to actually close it.

     

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