PostfixAdmin uses a session cookie when you login.
If you have login problems (for example, you can't login, but don't see an error message about wrong username/password), please test if cookies work as expected.
Please save the following code as cookie.php in the PostfixAdmin directory:
<?php
session_start();
echo session_id() . "<pre>";
var_dump($_SESSION);
$_SESSION['foo'] = 'works';
echo "\n\nCookies:\n";
var_dump($_COOKIE);
?>
Then open cookie.php in your browser - the first time, it should print the session ID and a list of your cookies. Reload it, and it should display the same session ID and additionally "works" as session content.
Typical problems:
Also check if you override one of the mentioned php.ini settings somewhere (if in doubt, check with phpinfo()).