KCF is KEGG Chemical Format, and is a 2D molecular graph format similar to XYZ.
Example, the KCF for phosphate is (taken from http://kegg.jp/dbget-bin/www_bget?C00009+-kcf ):
ATOM        5
            1   P1b P    27.1282  -21.2572
            2   O1c O    25.9971  -21.9011
            3   O1c O    28.4489  -21.8360
            4   O1c O    27.4637  -22.7728
            5   O1c O    27.1282  -19.9529
BOND        4
            1     1   2 1
            2     1   3 1
            3     1   4 1
            4     1   5 2