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film mode

summerfish
2007-08-08
2013-06-05
  • summerfish

    summerfish - 2007-08-08

    Hello,
    I am interested in calculating the surface band structure of a 22 layer thin film. Is there any particular setting within the program that lets me do that (as supposed to the bulk band structure)? I was looking over the Cr-mono example and didn't see anything indicating that it's a film other than the ngridk setting.
    Thank you.

     
    • exciting

      exciting - 2007-08-24

      All you need to do is have a vacuum layer (usually in the z-direction) sufficiently large for convergence of whatever you're trying to determine, and a k-point grid such that you have only one non-shifted k-point in the z-direction. For example:

      ngridk
        4  4  1

      vkloff
      0.25 0.5 0.0

       
    • summerfish

      summerfish - 2007-08-25

      Thank you for the reply. However, I have some follow up questions;
      1)By adding the vacuum layer, do you just mean changing the "vacuum" setting value to a number that's appropriate for convergence purposes?
      2)The primitive vectors of my system are not parallel to the c-axis, can the program handle that? That is, is it still possible to express the ngridk values in such a way to reflect that I am only computing over a couple of layers in the c-direction (thin film)?
      3)Are the basis functions used in the calculation two dimensional or three dimensional?

      I have tried running the input file below and it only gave me a band structure identical to the bulk structure:

      tasks
        0
        20

      spinorb
      .true.

      nempty
        10

      avec
        -0.5 -0.288675134595 0.86742992441  
        0.5  -0.288675134595 0.86742992441
        0.0   0.57735026919  0.86742992441

      scale1
        8.5665

      scale2
        8.5665

      scale3
        8.5665

      sppath
        '../../species/'

      ! note that the magnetic fields are in Cartesian coordinates
      atoms
        1                                     : nspecies
        'Bi.in'                               : spfname
        2                                     : natoms
        0.0 0.0 0.0   0.0 0.0 0.0   : atposl, bfieldc
        0.4682 0.4682 0.4682 0.0 0.0 0.0

      ngridk
        2  2  1

      vkloff
        0.5  0.5  0.0

      plot1d
        3 200                                 : nvp1d, npp1d
        0.0   0.5   0.5                       : vlvp1d
        0.0   0.0   0.0
        0.0   0.5   0.0

      Thank you.

       
      • exciting

        exciting - 2007-09-27

        Apologies for the delay in replying.

        The 'vacuum' variable only works in 'molecule' mode.

        In this case the vacuum refers to the empty space in the c-direction. This should be large enough to make the coupling between layer negligible. Your exciting.in file doesn't appear to have this vacuum layer.

        Regards,
        Kay.

         

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