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Cohesive energy of Fe

Elk Users
Praveen
2016-05-18
2016-05-19
  • Praveen

    Praveen - 2016-05-18

    Hello users,
    I am trying to calculate Fe cohesive energy. For that,I am trying to calculate single Fe atom energy. But though my input file seems correct,the energy doesn't converge. Could any of you please help me??? Thank you in advance :)

     
  • Markus

    Markus - 2016-05-18

    Dear Praveen,

    please show us your input, so we can tell if it is correct or not.

    In general, I find it difficult to obtain single-atom energies with the default basis set for the species. I'm usually happier with LAPW, which used to require some tuning of the species files.

    Markus

     
  • Praveen

    Praveen - 2016-05-19

    Hello Markus,
    Thank you for your response, Here are my input files for non-magnetic and magnetic Fe aroms.

    !Non-magnetic: Fe*****

    tasks
    0

    ! Adaptive linear mixing of the potential
    mixtype
    1

    ! PBE
    xctype
    20

    sppath
    '/home/elk-2.2.5/species/'

    avec
    18.89725989 0.000000000 0.000000000
    0.000000000 18.89725989 0.000000000
    0.000000000 0.000000000 18.89725989

    scale
    1

    autolinengy
    .true.

    beta0
    0.001

    betamax
    0.3

    atoms
    1 : nspecies
    'Fe.in' : spfname
    1 : natoms; atposl, bfcmt below
    0.50000000 0.50000000 0.50000000 0.00000000 0.00000000 0.00000000

    ngridk
    3 3 3

    autokpt
    .false.

    maxscl
    100000

    gmaxvr
    14

    vkloff
    0.5 0.5 0.5

    latvopt
    1

    spinpol
    .true.

    ! empty states
    nempty
    10

    ! convergence KS Potential
    epspot
    0.1e-5

    !force calculation
    tforce
    .true.

    and for Fe atom with non-zero magnetic moment the inputfile is as follows:

    !magnetic: Fe*****

    tasks
    0

    ! Adaptive linear mixing of the potential
    mixtype
    1

    ! PBE run first
    xctype
    20

    sppath
    '/home/elk-2.2.5/species/'

    avec
    18.89725989 0.000000000 0.000000000
    0.000000000 18.89725989 0.000000000
    0.000000000 0.000000000 18.89725989

    scale
    1

    autolinengy
    .true.

    beta0
    0.001

    betamax
    0.3

    atoms
    1 : nspecies
    'Fe.in' : spfname
    1 : natoms; atposl, bfcmt below
    0.50000000 0.50000000 0.50000000 0.00000000 0.00000000 0.00100000

    ngridk
    3 3 3

    autokpt
    .false.

    maxscl
    100000

    gmaxvr
    14

    vkloff
    0.5 0.5 0.5

    latvopt
    1

    spinpol
    .true.

    ! empty states
    nempty
    10

    ! convergence KS Potential
    epspot
    0.1e-5

    !force calculation
    tforce
    .true.

     

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