I'd like to know if it's possible to add the Administrative Tools (as menu) to the Start Menu on the second column, same as in the Win7 default Start Menu.
Yes. Go to the Customize Start Menu tab in the Settings.
Grab a Custom Command from the right column and drag it to the left column in the position you want to insert the new item.
Double-click on the new item.
Open the Link: dropdown and select Administrative Tools (it is probably the first item)
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