Content-Type: multipart/related; type="text/html"; boundary=Apple-Mail-96-685301812 --Apple-Mail-96-685301812 Content-Transfer-Encoding: quoted-printable Content-Type: text/html; charset=us-ascii Hi = all,

I've been thinking about this for a while and = finally got down to writing a prototype this Wednesday. What I wanted to = do was speed up the access of molecules (IAtomContainers) when accessing = data that will only be used by the CDK. This could for example be = retrieving structures from a MySQL/NoSQL database or transmitting = between components as required by Knime. The point is not to provide a = future-proof versioned format that other applications can read but to = provide a fast, flexible and efficient (in size) way of storing and = accessing molecules. Commonly we've been storing structures as mdl (not = very good) or CML text in a database. An alternative is to store the = bytes from Java's default 'ObjectOutputStream' or use a custom = serialisation library such as Kryo. Kryo is very nice but I didn't = really want to add a dependency for relatively trivial task. You also = have the problem that a format like CML/MDL may not store everything you = want and the serialisation may store too much (do you really want to = transmit ChemObjectListeners?).  

The = following prototype code is on branch in the package = org.openscience.cdk.io.stream which can be found here: https://github.com/johnmay/cdk/tree/= high-performance-serializer/src/main/org/openscience/cdk/io/stream

I defined two new interfaces IChemObjectInput<C = extends IChemObject> and IChemObjectOutput<C extends = IChemObject> that indicate binary IO,  Java uses = Reader/Writer suffix to indicate handling of text and automatic handling = of different char formats and I wanted to make it distinct that these = were binary input/output.  The idea was originally to have an = input/output for Containers, Atoms, Bonds etc.. and just assemble them = but unfortunately I had to defined separate ones for Atom and Bonds as = some atom/bond properties require the container to calculate their = value. I would much appreciate if anyone can see a way of simplifying = the API so I could use a common interface at the moment there's been a = lot of copy paste :-).

Anyways to the = syntax..

You can create an output and provided = select marshals that will write certain values. This example will write = atom number/symbol, pseudo label (IPseudoAtoms), 2D coordinates, = valency, formal charge for atoms and atom connections, order and stereo = for bonds.

IChemObjectOutput<IAtomContainer> out = =3D new AtomContainerOutput(out,
      =                     =                     =                   new = AggregatedAtomOutput(new AtomicNumberOutput(),
      =                     =                     =                 =    =  new PseudoLabelOutput(),
=            =              =                  new = Point2DOutput(),
              =                     =                     =            new = ValencyOutput(),
              =                     =                     =            new = FormalChargeOutput()),
      =                     =                     =                   new = AggregatedBondOutput(new SmallBondOutput(),
      =                     =                     =                     =                     =    new LargeBondOutput(),
      =                     =                     =                     =                     =    new BondOrderOutput(),
=               =                     =        new = BondStereoOutput()));

Each of the marshals (i.e. AtomicNumberOutput) is stateless and can = easily be defined anonymously, let's add one for atom id output (lambdas = will make this even easier in = future):

new = AtomOutputMarshal() {
    @Override
    public = void write(DataOutput out, IAtomContainer container, IAtom atom) throws = IOException {
        = out.writeUTF(atom.getID());
    = }
}

But what if getID returns a = null string? Well this is where some efficiency savings comes in. We can = check a field for a default value which means it won't get written to = the output (we can add any default value in when we = read). 

new = AtomOutputMarshal() {
    @Override
    public = void write(DataOutput out, IAtomContainer container, IAtom atom) throws = IOException {
        = out.writeUTF(atom.getID());
    = }

    @Override
  =   public boolean isDefault(IAtom atom) {
    =     return atom.getID() =3D=3D null;
    = }
}

Many output formats will = tag input field type and then write a value to indicate null. This = method defines a 'format' at the start of the atom stream. It's probably = a bit long to go into here but think of it like a 'fingerprint' that = indicates which fields should be
written/read for each atom = object. If you want to see it have a look at 'createAtomInput()' in this file: https:= //github.com/johnmay/cdk/blob/high-performance-serializer/src/main/org/ope= nscience/cdk/io/stream/atom/AggregatedAtomInput.java
Each = fingerprint is a single byte but you can nest 
<= div>
We also save on storage size. Most of the storage in = the stream is actually taken up by the 2D coordinates and it should be = possible to write a marshal that will only write coordinates to a = certain precission.
You can also wrap the output in a = 'DeflaterOutputStream' that will store ChEBI using the stream output in = ~3 Mb and only a small cost to speed.
<= div>This next one shows the same information as the first but is = intended to allow some rough calculations on how fast you could read = your data set. As a note I did some tests storing the bare minimum = (connections and atomic number) and managed to hit 96,000 molecules per = second
<= div>
If you're interested in the = values:

method time bytes megabytes flux
Stream 346 11716899 11.17410564 63739
SDF 4159 54285753 51.77092838 5302
CML 18605 95958030 91.51270866 1185
ObjectInputStream 5552 98481548 93.91932297 3972


As I said this was a = prototype to see if it was actually worth while implementing and would = greatly appreciate feedback and = thoughts.

Cheers,
J

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