The XSD editor is a cross-platform XML editor. Although it can be used to edit any type of XML file, the editor is specifically designed to allow easy creation, editing, and validation of XML Schema (XSD) files.
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jsXe is the Java Simple XML Editor. Out of the box it provides a tree view, DTD/Schema introspection and validation. It's aim is to provide a framework for XML editing through any number of views that can be loaded at runtime as plugins.
Kati is simplified schema-aware xml editor written in java. It supports just one fragment of the capabilities of XML Schema, but it enables a naive user to build a valid xml file with some clicks. Simply it does not allow the users to make mistakes.