PeerGuardian
PeerGuardian - a privacy oriented firewall application
... highly recommended to use PeerBlock instead, which is a continuation of PeerGuardian's development in Windows, with bug fixes and support for Windows Vista and Windows 7. Collaboration with peerblock.com is welcome!
PeerGuardian is an open project. Not only is its source code open for you to read, use, and modify - but the project is open for you to join and contribute in any form (code, documentation, bug reports, web and support).