RTS2 is project to create an open source environment for control of a fully autonomous observatory. It is running about dozen fully autonomous observatories. Its modular design allow easily addition of new devices (to already huge supported HW list).
L.E.I.C.A. (Long Exposure Internet CAmera) is an application that takes input from your webcam, or v4l2 device, and makes a long-exposure image.
Until now there's only a python binding for this app, soon there will be a C/C++ SDL one
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PyXPA is a Python interface to the XPA library (http://hea-www.harvard.edu/RD/xpa/ developed by the SAO/HEAD R&D Group (http://hea-www.harvard.edu/RD/)).