Goto PDF should be the first item by right-clicking the tex document.
I don't think so. IMHO the only reason for beeing first would be that access is faster. But even faster access to this function is available by Ctrl+LeftClick. So it's actually a rarely used function for the context menu.
What about writting this keyboard shortcut (Ctrl+LeftClick) in the window opened by right-clicking the document ? (just in front of 'Goto PDF' like for other shortcuts).
This would made aware of that faster access (which I've just discovered through that post ;-)