There is an 'accelerator' method which does what I think you want but I've never been able to make it work. You can fake some of it if the keystroke has an associated number value.
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> Sent: Thursday, May 16, 2002 20:11
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> Subject: [perl-win32-gui-users] keystrokes
> hi. is there any way of associating a keystroke with
> something, like alt+s
> to bring up a settings window?
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