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If I close KPS while its window is flush with the left border of the Windows XP Desktop, the next time I open the program, its window shifts to the horizontal center of the Desktop. Is there a way to force KPS to always remember its window position and size?
KeePass keeps window position in it's ini file. e.g.
Try changing the values in the ini file before running KeePass.
Works for your values; however, if I set KeeWindowPX to zero (i.e. KeeWindowPX=0) the window does not open flush with the left side of the screen as it should. Instead, it opens centered horizontally.
Sounds like a bug - time for a bug report.