From: Bob H. <ha...@st...> - 2008-04-03 21:23:16
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Angel Herráez wrote: >So I've being playing for a few days with the minimization of structures in Jmol, and I'm very >happy with the result; I think it will make an excellent educational tool. I'm feeding Jmol with >2D structures drawn and then exported into MOL format. >(All this runs within a single web page, though I'm not ready yet to go public with it.) > >One thing I miss, and would be interesting to have, but likely not trivial to implement, is >retention of the stereochemistry. > > that's next. I have an idea but no time to work on it. It would involve the MOL2 format bond stereochemistry designations. >Despite being 2D, formula drawing programs allow to put wedge bonds (up/down), and at >least JChemPaint exports them correctly into MOL format. However, since the Z coordinate >is zero for all atoms, that stereo info is lost. > >I can think of a way to set some positive or negative Z value on each atom depending on >the type of stereo bond (even using Javascript) and so modifiy the MOL before giving it to >Jmol, but then I'd need that Jmol retains that configuration, which it is not doing right now >upon minimization. > > > Try at least setting Z values differently for the different atoms. Are all the H atoms there? It will help a lot if the H atoms are on the carbons that might otherwise invert. >I realize the implications for the calculation are heavy, and it may even be undesirable to >have it active by default --could be a toggle option--. > > > Many others have struggled with this -- we will not solve it in a day. But if you can experiment with setting those Z values, if you come up with something relatively simple, I might be able to implement it. Bob >Any insights? > > >------------------------------------------------------------------------- >Check out the new SourceForge.net Marketplace. >It's the best place to buy or sell services for >just about anything Open Source. >http://ad.doubleclick.net/clk;164216239;13503038;w?http://sf.net/marketplace >_______________________________________________ >Jmol-developers mailing list >Jmo...@li... >https://lists.sourceforge.net/lists/listinfo/jmol-developers > > -- Robert M. Hanson Professor of Chemistry St. Olaf College Northfield, MN http://www.stolaf.edu/people/hansonr If nature does not answer first what we want, it is better to take what answer we get. -- Josiah Willard Gibbs, Lecture XXX, Monday, February 5, 1900 |